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FUR4Sustain

European network of FURan based chemicals and materials FOR a Sustainable

development

CA18220

Funded by the Horizon 2020 Framework Programme of the European Union

OBJECTIVE 

Gathering pan-European experts to promote furan-based polymers industrialization and market-introduction

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The Fur4Sustain project is a European COST Action project. COST Actions are funded by the European Cooperation in Science and Technology (COST). They are projects aiming at the creation of research networks, that allow the collaboration among scientists across Europe, thus giving impetus to research advancements and innovation.

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From cling film and clothing to satellites and spacecrafts, modern societies rely heavily on plastics. Plastics are polymers, i.e. long chain molecules constructed by the repetition of a single unit, the monomer. Poly(ethylene terephthalate) (PET) is a well-known polymer used for plastic bottles, amongst other. Nowadays, most of these materials are fossil-based, in other words, their production depends on petroleum. With growing depletion of oil fields and fluctuating prices of crude oil such a dependence creates great concerns. Moreover, environmental issues are one of the major challenges of the 21st century and greener, more sustainable alternatives to fossil-based materials are demanded by consumers.

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In this context, a great deal of effort has been put into exploiting renewable feedstock, notably biomass, and especially low-value biomass waste. 2,5-furandicarboxylic acid (FDCA) is an extremely promising bio-based monomer, derived from furfural or 5-hydroxymethyl furfural, which are isolated from biomass carbohydrates. For example, poly(ethylene furanoate), prepared from FDCA, is a bio-based polymer with comparable or better performances than PET. Despite the recent progresses witnessed in the synthesis of FDCA and FDCA-based polymers, the development of FDCA-based products is hampered by the lack of communication among research groups and the paucity of collaborations between Academy and Industry.

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The Fur4Sustain project aims at rallying individual research efforts scattered across Europe, gathering experts in FDCA synthesis, polymer science and materials development, along with producer, manufacture and recycling industrial stakeholders, as well as techno-economic viability experts. Through this project, new technologies for the synthesis of FDCA, especially from non-edible sources of carbohydrates, will be developed and novel furan-based polymers will be synthesized. In a “holistic” approach, taking into account FDCA synthetic routes and polymers development, as well as key technical, economic, environmental and social factors, the Action will identify and support solutions for the successful market introduction of sustainable, furan-based products. Finally, the Fur4Sustain action is an open platform for collaboration and networking, fostering the development of intersectorial knowledge.

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Action Chair: Dr Andreia F. SOUSA 
Action Vice Chair: Dr Nathanael GUIGO 
Action Science Officer: Dr Mónica PÉREZ-CABERO 
Administrative Officer: Ms Carmencita MALIMBAN 

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Professor Bikiaris is part of the core group of the action and leader of WG2: Materials development, their processing and characterisation, and computational studies.

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More information on how to join the action can be found here

To follow our group's research on FDCA polyesters click here

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List of papers published in the context of Fur4Sustain from BikiarisLab:

  1. Synthesis and characterization of novel polymer/clay nanocomposites based on poly (butylene 2,5-furan dicarboxylate)

  2. Interfacial Interactions, Crystallization, and Molecular Dynamics of Renewable Poly(Propylene Furanoate) In Situ Filled with Initial and Surface Functionalized Carbon Nanotubes and Graphene Oxide

  3. Tuning the Properties of Furandicarboxylic Acid-Based Polyesters with Copolymerization: A Review

  4. Calorimetric and Dielectric Study of Renewable Poly(hexylene 2,5-furan-dicarboxylate)-Based Nanocomposites In Situ Filled with Small Amounts of Graphene Platelets and Silica Nanoparticles

  5. Towards High Molecular Weight Furan-Based Polyesters: Solid State Polymerization Study of Bio-Based Poly(Propylene Furanoate) and Poly(Butylene Furanoate)

  6. Molecular Dynamics in Nanocomposites Based on Renewable Poly(butylene 2,5-furan-dicarboxylate) In Situ Reinforced by Montmorillonite Nanoclays: Effects of Clay Modification, Crystallization, and Hydration

  7. A Facile Method to Synthesize Semicrystalline Poly(ester amide)s from 2,5-Furandicarboxylic Acid, 1,10-Decanediol, and Crystallizable Amido Diols

  8. Effect of additives on the thermal and thermo-oxidative stability of poly(ethylene furanoate) biobased polyester

  9. Tuning thermo-mechanical properties of poly(lactic acid) films through blending with bioderived poly(alkylene furanoate)s with different alkyl chain length for sustainable packaging

  10. Unlocking the potential of furan-based poly(ester amide)s: An investigation of crystallization, molecular dynamics and degradation kinetics of novel poly(ester amide)s based on renewable poly(propylene furanoate)

  11. Mechanical and Functional Properties of Novel Biobased Poly(decylene-2,5-furanoate)/Carbon Nanotubes Nanocomposite Films

  12. Towards increased sustainability for aromatic polyesters: Poly(butylene 2,5-furandicarboxylate) and its blends with poly(butylene terephthalate)

  13. Poly(propylene vanillate): A Sustainable Lignin-Based Semicrystalline Engineering Polyester

  14. A New Era in Engineering Plastics: Compatibility and Perspectives of Sustainable Alipharomatic Poly(ethylene terephthalate)/Poly(ethylene 2,5-furandicarboxylate) Blends

  15. Investigation of the catalytic activity and reaction kinetic modeling of two antimony catalysts in the synthesis of poly(ethylene furanoate)

  16. Multifunctionality of Reduced Graphene Oxide in Bioderived Polylactide/Poly(Dodecylene Furanoate) Nanocomposite Films

  17. Effectiveness of Esterification Catalysts in the Synthesis of Poly(Ethylene Vanillate)

  18. Molecular mobility investigation of the biobased Poly(ethylene vanillate) and Poly(propylene vanillate)

  19. Recommendations for replacing PET on packaging, fiber, and film materials with biobased counterparts

  20. Tuning thermal properties and biodegradability of poly(isosorbide azelate) by compositional control through copolymerization with 2,5-furandicarboxylic acid

  21. Towards novel lignin-based aromatic polyesters: In-depth study of the thermal degradation and crystallization of poly(propylene vanillate)

  22. Poly(ethylene furanoate-co-ethylene vanillate) biobased copolymers: Impact of the incorporation of vanillic acid units in poly(ethylene furanoate)

  23. Compatibilization of Polylactide/Poly(ethylene 2,5-furanoate) (PLA/PEF) Blends for Sustainable and Bioderived Packaging

  24. Blending PLA with Polyesters Based on 2,5-Furan Dicarboxylic Acid: Evaluation of Physicochemical and Nanomechanical Properties

  25. Poly(hexylene vanillate): Synthetic Pathway and Remarkable Properties of a Novel Alipharomatic Lignin-Based Polyester

  26. Bio-based additive manufacturing materials: An in-depth structure-property relationship study of UV-curing polyesters from itaconic acid

  27. Influence of bio-based 2,5-furandicarboxylic acid on the properties of water-borne polyurethane dispersions

  28. UV-Curing Additive Manufacturing of Bio-Based Thermosets: Effect of Diluent Concentration on Printing and Material Properties of Itaconic Acid-Based Materials

  29. Synthesis and thermal investigation of poly(propylene terephthalate-co-2,5-furan dicarboxylate) copolyesters

  30. Biobased plastics for the transition to a circular economy

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